Metallic Salts of Ammono Acids.

نویسنده

  • E C Franklin
چکیده

The Action of Liquid-Ammonia Solutions of Ammono Acids on Metallic Amides, Imides, and Nitrides. The acid amides and imides, and the metallic derivatives of the acid amides and imides are the acds, bases, and salts respectively of an ammonia system of acids, bases, and salts.1 Guided by the relationships implied in the above statement Franklin and Stafford were able to prepare potassium derivatives of a considerable number of acid amides by the action of potassium amide on certain acid amides in solution in liquid ammonia. That is to say, an ammono base, potassium amide, was found to react with ammono acids in liquid ammonia to form ammono salts just as the aquo base, potassium hydroxide, acts upon aquo acids in water solution to form aquo salts. Choosing, for example, benzamide and benzoic acid as representative acids of the two systems, the analogous reactions taking place respectively in liquid ammonia and water are represented by the equations:

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عنوان ژورنال:
  • Proceedings of the National Academy of Sciences of the United States of America

دوره 1 2  شماره 

صفحات  -

تاریخ انتشار 2005